上海中科神光光电产业有限公司
光电材料事业部
技术参数

    GGG(12.373 Å)与YIG(12.376 Å)的晶格常数接近,是被广泛采用的YIG磁光薄膜的衬底材料,但为了提高磁光薄膜的磁光优值,有时需要选择晶格常数较大的衬底单晶,GSGG是GGG晶体中八面体的 2个Ga被离子半径较大的Sc取代,从而具有较大的晶格常数。上世纪80年代,由于Sc原料非常昂贵,因此采用CaMgZrGGG(12.480 Å)取代GSGG,近年来,提纯技术的进步,Sc原料价格大幅下降,具有大晶格常数的GSGG(12.554 Å)单晶衬底将越来越获得广泛的应用。      表1 几种含镓石榴石晶体的晶格常数  

Crystal name GGG YSGG CaMgZr:GGG GYSGG GSGG
Lattice constant (Å) 12.373 12.426 12.480 12.507 12.554
(444) diffractive angle (2θ) 51 º7' 50 º44' 50 º43' 50 º 40' 50.22'
                GGG (Gd3Ga5O12)   GGG (Gd3Ga5O12)   GaMgZr:GGG (Gd2.6Ca0.4)(Ga4.1Mg0.25Zr0.65)O12   GYSGG (Gd0.63Y2.37Sc2Ga3O12)   GSGG (Gd3Sc2Ga3O12)

  GSGG                      YSGG                              GSYGG

Crystal GSGG
Molecular formula Gd3Sc2Ga3O12
Crystal system Cubic
Point group Oh10
Space group Ia3d
Molecular weight 962.8
Melting point (℃) 1820
Density (g/cm3) 6.44
Moss hardness 7.1
Lattice constant (Å) 12.554
Thermal expand coefficient (10-6K-1) 7.4
Thermal conductivity (W·m-1·K-1) 6
Refractive index (@1μm) 1.94
Phonon energy (cm-1) 741
<111> diffraction angle 25°11'
Refractive index temperature coefficient ( )×10-6,℃-1 10.5
Sellmeier equation ,S=2.734,λ0=1.0321;λ:μm
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